| Records |
Author  |
Zou, L.H. |
| Title |
Sulfide precipitation flotation for treatment of acidic mine waste water |
Type |
Journal Article |
| Year |
2000 |
Publication |
Transactions of Nonferrous Metals Society of China |
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| Volume |
10 |
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Pages |
106-109 |
| Keywords |
mine water treatment |
| Abstract |
Sulfide precipitation flotation of copper-iron-bearing acidic waste water from a large copper mine and the stimulated waste water were studied. The pH of the waste water was 2.2, with 130 mg/L Cu2+ and 500 mg/L Fe3+ (Fe2+). Results show that, when Na2S was added as precipitating agent, sodium butylxanthate as collector and at pH 2.0, the removal of copper could be as high as 99.7 % and the residual copper decreased to 0.2 mg/L, however, almost no iron was removed. When the floated solution was neutralized to pH = 8.0, more than 98 % iron was precipitated and the residual iron was less than 10 mg/L. In experiment on actual mine effluents, after the use of precipitate flotation technology to recover copper and pH neutralization to precipitate iron, the treated waste water does meet the emission standards for sewage and valuable floating copper graded 37.12%. The chemical calculation and mechanism of solution were also presented. |
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Sulfide precipitation flotation for treatment of acidic mine waste water; Wos:000088249500025; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17086 |
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128 |
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| Author |
Zhuang, J.M. |
| Title |
Lignor(TM) process for acidic rock drainage treatment |
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Journal Article |
| Year |
2004 |
Publication |
Environ. Technol. |
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25 |
Issue |
9 |
Pages |
1031-1040 |
| Keywords |
mine water treatment |
| Abstract |
The process using lignosulfonates for acidic rock drainage (ARD) treatment is referred to as the Lignor(TM) process. Lignosulfonates are waste by-products produced in the sulfite pulping process. The present study has shown lignosulfonates are able to protect lime from developing an external surface coating, and hence to favor its dissociation. Further, the addition of lignosulfonates to ARD solutions increased the clotting and settling rate of the formed sludge. The capability of lignosulfonates to form stable metal-lignin complexes makes them very useful in retaining metal ions and thus improving the long-term stability of the sludge against leaching. The Lignor(TM) process involves metal sorption with lignosulfonates, ARD neutralization by lime to about pH 7, pH adjustment with caustic soda to 9.4 – 9.6, air oxidation to lower the pH to a desired level, and addition of a minimum amount of FeCl3 for further removal of dissolved metals. The Lignor(TM) process removes all concerned metals (especially Al and Mn) from the ARD of the Britannia Mine (located at Britannia Beach, British Columbia, Canada) to a level lower than the limits of the B.C. Regulations. Compared with the high-density sludge (HDS) process, the Lignor(TM) process has many advantages, such as considerable savings in lime consumption, greatly reduced sludge volume, and improved sludge stability. |
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Lignor(TM) process for acidic rock drainage treatment; Wos:000224971800006; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16998 |
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117 |
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Zaluski, M. |
| Title |
Design and construction of bioreactors with sulfate-reducing bacteria for acid mine drainage control |
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Journal Article |
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1999 |
Publication |
Phytoremediation and Innovative Strategies for Specialized Remedial Applications |
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205-210 |
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mine water treatment |
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At many abandoned mine sites in the Western U.S., conventional treatment of AMD is not feasible due to the of lack of power and limited site accessibility. Therefore, three bioreactors were built at an abandoned mine site in Montana to demonstrate feasibility of treating AMD using sulphate reducing bacteria (SRB) in a passive water treatment train. The SRB are capable of increasing the pH and reducing the load of dissolved metals in the effluent. The reactors, constructed in the Fall of 1998, were designed to evaluate the SRB technology applied under different environmental conditions. Each bioreactor was designed with mechanisms to enable simulation of seasonal dry and wet climatic conditions. Two bioreactors were placed in trenches and one was constructed above the ground to investigate impact of seasonal freezing and thawing on SRB activity. Two bioreactors contain a passive pretreatment section to increase pH of water before the AMD enters the bioreactor chamber. |
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Design and construction of bioreactors with sulfate-reducing bacteria for acid mine drainage control; Isip:000082416500033; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17136 |
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177 |
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| Author |
Younger, P.L. |
| Title |
Passive in situ remediation of acidic mine waste leachates: progress and prospects |
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Journal Article |
| Year |
2003 |
Publication |
Land Reclamation: Extending the Boundaries |
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253-264 |
| Keywords |
mine water treatment |
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The reclamation of former mining sites is a major challenge in many parts of the world. In relation to the restoration of spoil heaps (mine waste rock piles) and similar bodies of opencast backfill, key challenges include (i) the establishment of stable slopes and minimization of other geotechnical hazards (ii) developing and maintaining a healthy vegetative cover (iii) managing the hydrological behaviour of the restored ground. Significant advances have been made over the past four decades in relation to all four of these objectives. One of the most recalcitrant problems is the ongoing generation and release of acidic leachates, which typically emerge at the toes of (otherwise restored) spoil heaps in the form of springs and seepage areas. Such features are testament to the presence of a “perched” groundwater circulation system within the spoil, and their acidity reflects the continued penetration of oxygen to zones within the heaps which contain reactive pyrite (and other iron sulphide minerals). Two obvious strategies for dealing with this problem are disruption of the perched groundwater system and/or exclusion of oxygen entry. These strategies are now being pursued with considerable success where spoil is being reclaimed for the first time, by the installation of two types of physical barrier (dry covers and water covers). However, where a spoil heap has already been revegetated some decades ago, the destruction of an established sward or woodland in order to retro-fit a dry cover or water cover is rarely an attractive option for dealing with the “secondary dereliction” represented by ongoing toe seepages of acidic leachates. More attractive by far are passive treatment techniques, in which the polluted water is forced to flow through reactive media which serve to neutralize its acidity and remove toxic metals from solution. A brief historical review of the development of such systems reveals a general progression from using limestone as the key neutralizing agent, through a combined use of limestone and compost, to systems in which almost all of the neutralization is achieved by means of bacterial sulphate reduction in the saturated compost media of subsurface-flow bioreactors. In almost all cases, these passive treatment systems include an aerobic, surface flow wetland as the final “polishing” step in the treatment process. Such wetlands combine treatment functions (efficient removal of metals from the now-neutralized waters down to low residual concentrations, and re-oxygenating the water prior to discharge to receiving watercourses) with amenity value (attractive areas for recreational walking, bird-watching etc) and ecological value. |
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Passive in situ remediation of acidic mine waste leachates: progress and prospects; Isip:000183447100035; Times Cited: 0; ISI Web of Science |
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no |
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CBU @ c.wolke @ 17016 |
Serial |
158 |
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| Author |
Ye, Z.H. |
| Title |
Removal and distribution of iron, manganese, cobalt, and nickel within a Pennsylvania constructed wetland treating coal combustion by-product leachate |
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Journal Article |
| Year |
2001 |
Publication |
Journal of Environmental Quality |
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30 |
Issue |
4 |
Pages |
1464-1473 |
| Keywords |
mine water treatment |
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A flow-through wetland treatment system was constructed to treat coal combustion by-product leachate from an electrical power station at Springdale, Pennsylvania. In a nine-compartment treatment system, four cattail (Typha latifolia L.) wetland cells (designated Cells I through 4) successfully removed iron (Fe) and manganese (Mn) from the inlet water; Fe and Mn concentrations were decreased by an average of 91% in the first year (May 1996-May 1997), and by 94 and 98% in the second year (July 1997-June 1998), respectively. Cobalt (Co) and nickel (Ni) were decreased by an average of 39 and 47% in the first year, and 98 and 63% in the second year, respectively. Most of the metal removed by the wetland cells was accumulated in sediments, which constituted the largest sink. Except for Fe, metal concentrations in the sediments tended to be greater in the top 5 em of sediment than in the 5- to 10- or 10- to 15-cm layers, and in Cell I than in Cells 2, 3, and 4. Plants constituted a much smaller sink for metals; only 0.91, 4.18, 0.19, and 0.38% of the Fe, Mn, Co, and Ni were accumulated annually in the aboveground tissues of cattail, respectively. A greater proportion of each metal (except Mn) was accumulated in cattail fallen litter and submerged Chara (a macroalga) tissues, that is, 2.81, 2.75, and 1.05% for Fe, Co, and Ni, respectively. Considerably higher concentrations of metals were associated with cattail roots than shoots, although Mn was a notable exception. |
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Removal and distribution of iron, manganese, cobalt, and nickel within a Pennsylvania constructed wetland treating coal combustion by-product leachate; Wos:000174863000040; Times Cited: 15; ISI Web of Science |
Approved |
no |
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CBU @ c.wolke @ 17061 |
Serial |
122 |
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