Benner, S. G., Blowes, D. W., & Ptacek, C. J. (1997). A full-scale porous reactive wall for prevention of acid mine drainage. Ground Water Monitoring and Remediation, 17(4), 99–107.
Abstract: The generation and release of acidic drainage containing high concentrations of dissolved metals from decommissioned mine wastes is an environmental problem of international scale. A potential solution to many acid drainage problem is the installation of permeable reactive walls into aquifers affected by drainage water derived from mine waste materials. A permeable reactive wall installed into an aquifer impacted by low-quality mine drainage waters was installed in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The reactive mixture, containing organic matter, was designed to promote bacterially mediated sulfate reduction and subsequent metal sulfide precipitation. The reactive wall is installed to an average depth of 12 feet (3.6 m) and is 49 feet (15 m) long perpendicular to ground water flow. The wall thickness (flow path length) is 13 feet (4 m). Initial results, collected nine months after installation, indicate that sulfate reduction and metal sulfide precipitation is occurring. Comparing water entering the wall to treated water existing the wall, sulfate concentrations decrease from 2400 to 4600 mg/L to 200 to 3600 mg/L; Fe concentration decrease from 250 to 1300 mg/L to 1.0 to 40 mg/L, pH increases from 5.8 to 7.0; and alkalinity (as CaCO<inf>3</inf>) increases from 0 to 50 mg/L to 600 to 2000 mg/L. The reactive wall has effectively removed the capacity of the ground water to generate acidity on discharge to the surface. Calculations based on comparison to previously run laboratory column experiments indicate that the reactive wall has potential to remain effective for at least 15 years.
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Bowell, R. J. (2004). (P. Jarvis Adam, A. Dudgeon Bruce, & L. Younger Paul, Eds.). mine water 2004 – Proceedings International Mine Water Association Symposium. 2: University of Newcastle.
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Li, L., Jiang, Y., & Guo, Y. (1999). Research on a comprehensive industrialization technology for the treatment of mining water containing sulfate ions. Meitian Dizhi Yu Kantan = Coal Geology & Exploration, 27(6), 51–53.
Abstract: A method using a barium reagent was developed for the purification of the higher-sulphate mine water.
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Mustikkamaki, U. - P. (2000). Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation. Vuoriteollisuus = Bergshanteringen, 58(1), 44–47.
Abstract: Acid mine drainage (AMD) is one of the most serious environmental problems in the metal-mining industry. AMD is formed by the chemical and bacterial oxidation of sulphide minerals, and it is characterized by low pH values and high sulphate and metals content. The most common method to treat AMD is chemical neutralization. The chemical treatment requires high capital and operating costs and its use is problematic at the closed mines sites. Outokumpu has studied and used sulphate reducing bacteria (SRB) as an alternative method for the treatment of AMD. SRB existing in many natural anaerobic aqueous environments can reduce sulphate to sulphide which precipitates metals as extremely insoluble metal sulphides. Full scale experiments were begun in summer 1995 in the Ruostesuo open pit (depth 46 m) by adding liquid manure as a source of bacteria and press-juice as a growth substrate. The average Zn content of the whole column has decreased from 3,5 mg/l to 0,8 mg/l and below 25 m zinc is 0 mg/l. Similar results have been reached with nickel in the Kotalahti old nickel mine, where bacteria were brought in 1996. We have found that the same bacterial mechanism acts in peat-limestone filters, which Outokumpu has built at several mine sites since 1993.
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Kuyucak, N. (2001). Acid mining drainage prevention and control. Mining Environmental Management, 9(1), 12–15.
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