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Author Burt, R.A.; Caruccio, F.T.
Title The effect of limestone treatments on the rate of acid generation from pyritic mine gangue Type Journal Article
Year 1986 Publication Environmental geochemistry and health Abbreviated Journal
Volume 8 Issue Pages 8
Keywords mine water treatment
Abstract Surface water enters the Haile Gold Mine, Lancaster County, South Carolina by means of a small stream and is ponded behind a dam and in an abandoned pit. This water is affected by acidic drainage. In spite of the large exposures of potentially acid producing pyritic rock, the flux of acid to the water is relatively low. Nevertheless, the resulting pH values of the mine water are low (around 3.5) due to negligible buffering capacity. In view of the observed low release of acidity, the potential for acid drainage abatement by limestone ameliorants appears feasible. This study investigated the effects of limestone treatment on acid generation rates of the Haile mine pyritic rocks through a series of leaching experiments. Below a critical alkalinity threshold value, solutions of dissolved limestone were found consistently to accelerate the rate of pyrite oxidation by varying degrees. The oxidation rates were further accelerated by admixing solid limestone with the pyritic rock. However, after a period of about a month, the pyrite oxidation rate of the admixed samples declined to a level lower than that of untreated pyrite. Leachates produced by the pyrite and limestone mixtures contained little if any iron. Further, in the mixtures, an alteration of the pyrite surface was apparent. The observed behaviour of the treated pyrite appears to be related to the immersion of the pyrite grains within a high alkalinity/high pH environment. The high pH increases the rate of oxidation of ferrous iron which results in a higher concentration of ferric iron at the pyrite surface. This, in turn, increases the rate of pyrite oxidation. Above a threshold alkalinity value, the precipitation of hydrous iron oxides at the pyrite surface eventually outpaces acid generation and coats the pyrite surface, retarding the rate of pyrite oxidation.
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ISSN 0269-4042 ISBN (up) Medium
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Notes Sept; The effect of limestone treatments on the rate of acid generation from pyritic mine gangue; London: Chapman & Hall; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7021.pdf; Opac Approved no
Call Number CBU @ c.wolke @ 7021 Serial 14
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Author Bochkarev, G.R.; Beloborodov, A.V.; Kondrat'ev, S.A.; Pushkareva, G.I.
Title Intensification of Aeration in treating Natural-Water and Mine Water Type Journal Article
Year 1994 Publication J. Min. Sci. Abbreviated Journal
Volume 30 Issue 6 Pages 5
Keywords mine water treatment
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ISSN 1062-7391 ISBN (up) Medium
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Notes Nov; Intensification of Aeration in treating Natural-Water and Mine Water; New York: Consultants Bureau; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7033.pdf; Opac Approved no
Call Number CBU @ c.wolke @ 7033 Serial 15
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Author Erten-Unal, M.; Wixson, B.G.
Title Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA Type Journal Article
Year 1999 Publication Water Air Soil Pollut. Abbreviated Journal
Volume 116 Issue 3-4 Pages 501-522
Keywords biotreatment lead and zinc mine wastewater MINTEQ speciation biotreatment lead and zinc mine wastewater minteq speciation trout salmo-gairdneri water
Abstract Continued mining development in the world's largest lead producing area has generated and increased concern over effective mine water treatment in Missouri's New Lead Belt. A new type of mine/mill wastewater treatment system was constructed which consisted of a tailings pond followed by a series of artificially constructed meandering biotreatment channels and a polishing lagoon. This system provided additional retention time and distance for the removal of heavy metals by abundant aquatic plants and sedimentation. Seasonal field sampling and analytical testing that evaluated the present system confirmed that it provided good treatment for removal of heavy metals within the company property and produced a final effluent within the state and federal regulatory guidelines. On average, greater than 95% of zinc and manganese in the drainage water were removed by the biotreatment system, while lead and copper were 50 to 60%. A chemical equilibrium model, MINTEQ, was also used to identify various species of lead and zinc in the biotreatment system. The model predicted that the major species of carbonates and hydroxides would be the predominant complexes of lead and zinc for the pH and alkalinity values reported in the biotreatment system. These results were also supported by the literature.
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ISSN 0049-6979 ISBN (up) Medium
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Notes Dec.; Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA; Isi:000083273200004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10115.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 17472 Serial 16
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Author Chen, M.; Li, L.; Grace, J.; Tazaki, K.; Shiraki, K.; Asada, R.; Watanabe, H.
Title Remediation of acid rock drainage by regenerable natural clinoptilolite Type Journal Article
Year 2007 Publication Water, Air, Soil Pollut. Abbreviated Journal
Volume 180 Issue 1-4 Pages 11-27
Keywords mine water treatment
Abstract Clinoptilolite is investigated as a possible regenerable sorbent for acid rock drainage based on its adsorption capacity for Zn, adsorption kinetics, effect of pH, and regeneration performance. Adsorption of Zn ions depends on the initial concentration and pH. Adsorption/Desorption of Zn reached 75% of capacity after 1-2 h. Desorption depended on pH, with an optimum range of 2.5 to 4.0. The rank of desorption effectiveness was EDTAEDTA > NaCl > NaNO3 > NaOAc > NaHCO3 > Na2CO3 > NaOH > CeCa(OH)(2). For cyclic absorption/desorption, adsorption remained satisfactory for six to nine regenerations with EDTA and NaCl, respectively. The crystallinity and morphology of clinoptilolite remained intact following 10 regeneration cycles. Clinoptilolite appears to be promising for ARD leachate treatment, with significant potential advantages relative to current treatment systems.
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Notes Mar; Remediation of acid rock drainage by regenerable natural clinoptilolite; Wos:000244030000003; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 7319 Serial 17
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Author Banks, D.; Younger, P.L.; Arnesen, R.-T.; Iversen, E.R.; Banks, S.B.
Title Mine-water chemistry: The good, the bad and the ugly Type Journal Article
Year 1997 Publication Environ. Geol. Abbreviated Journal
Volume 32 Issue 3 Pages 157-174
Keywords mine water treatment mine-water chemistry acid mine drainage mine-water pollution mine-water treatment county-durham drainage movements Pollution and waste management non radioactive Groundwater problems and environmental effects mine drainage contamination hydrogeochemistry mine water drainage acid mine drainage
Abstract Contaminative mine drainage waters have become one of the major hydrogeological and geochemical problems arising from mankind's intrusion into the geosphere. Mine drainage waters in Scandinavia and the United Kingdom are of three main types: (1) saline formation waters; (2) acidic, heavy-metal-containing, sulphate waters derived from pyrite oxidation, and (3) alkaline, hydrogen-sulphide-containing, heavy-metal-poor waters resulting from buffering reactions and/or sulphate reduction. Mine waters are not merely to be perceived as problems, they can be regarded as industrial or drinking water sources and have been used for sewage treatment, tanning and industrial metals extraction. Mine-water problems may be addressed by isolating the contaminant source, by suppressing the reactions releasing contaminants, or by active or passive water treatment. Innovative treatment techniques such as galvanic suppression, application of bactericides, neutralising or reducing agents (pulverised fly ash-based grouts, cattle manure, whey, brewers' yeast) require further research.
Address D. Banks, Norges Geologiske Undersokelse, Postboks 3006 – Lade, N-7002 Trondheim, Norway
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ISSN 0943-0105 ISBN (up) Medium
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Notes Oct.; Mine-water chemistry: The good, the bad and the ugly; 0337169; Germany 78; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10620.pdf; Geobase Approved no
Call Number CBU @ c.wolke @ 10620 Serial 18
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