| Records |
| Author |
Barton, C.D.; Karathanasis, A.D. |
| Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
| Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
Abbreviated Journal |
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Issue |
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Pages |
1545 |
| Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
| Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
Place of Publication |
81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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| Call Number |
CBU @ c.wolke @ 16630 |
Serial |
70 |
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| Author |
Cravotta, C.A., III; Watzlaf, G.R.; Naftz, D.L.; Morrison, S.J.; Fuller, C.C.; Davis, J.A. |
| Title |
Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients |
Type |
Book Chapter |
| Year |
2002 |
Publication |
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Abbreviated Journal |
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Issue |
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Pages |
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| Keywords |
acid mine drainage; alkaline earth metals; aquatic environment; aquifers; calcium; carbonate rocks; chemical properties; construction; construction materials; crushed stone; dissolved materials; drainage; effluents; ground water; limestone; magnesium; metals; pH; pollution; porous materials; precipitation; retention; saturation; sedimentary rocks; sulfate ion; suspended materials 22, Environmental geology |
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Academic Press |
Place of Publication |
Amsterdam |
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ISBN |
0125135637 |
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Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients; GeoRef; English; 2004-040518; References: 66; illus. incl. 4 tables |
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| Call Number |
CBU @ c.wolke @ 5686 |
Serial |
81 |
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| Author |
Karathanasis, A.D.; Barton, C.D. |
| Title |
The revival of a failed constructed wetland treating a high Fe load AMD |
Type |
Book Chapter |
| Year |
1999 |
Publication |
Proceedings; biogeochemistry of trace elements in coal and coal combustion byproducts |
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Pages |
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abandoned mines acid mine drainage anaerobic environment carbonate rocks characterization composting constructed wetlands design environmental analysis ferrihydrite geologic hazards hydrology hydroxides iron iron hydroxides Kentucky limestone metals minerals mines organic compounds oxides pollution remediation runoff sedimentary rocks sediments solubility sulfate ion United States water quality water treatment wetlands 22, Environmental geology |
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Kluwer Academic/Plenum Publishers |
Place of Publication |
New York |
Editor |
Sajwan, K.S.; Alva, A.K.; Keefer, R.F. |
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ISBN |
0306462885 |
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The revival of a failed constructed wetland treating a high Fe load AMD; GeoRef; English; 2002-039561; Fourth international conference on the Biogeochemistry of trace elements, Berkeley, CA, United States, June 23, 1997 References: 45; illus. incl. 2 tables, sketch maps |
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| Call Number |
CBU @ c.wolke @ 16571 |
Serial |
82 |
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| Author |
Ziemkiewicz, P.F.; Meek, F.A., Jr.; Skousen, J.G.; Ziemkiewicz, P.F. |
| Title |
Long term behavior of acid forming rock; results of 11-year field studies |
Type |
Book Chapter |
| Year |
1996 |
Publication |
Acid mine drainage control and treatment |
Abbreviated Journal |
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Issue |
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Pages |
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| Keywords |
acid mine drainage; acid rock drainage; alkaline earth metals; alkalinity; calcium; chemical composition; clastic rocks; coal mines; leachate; metals; mines; pH; pollution; prediction; reclamation; remediation; sandstone; sedimentary rocks; shale; spoils; sulfate ion; sulfur; United States; Upshur County West Virginia; waste disposal; waste rock; weathered materials; weathering; West Virginia 22, Environmental geology |
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West Virginia University and the National Mine Land Reclamation Center |
Place of Publication |
Morgantown |
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Long term behavior of acid forming rock; results of 11-year field studies; GeoRef; English; 2004-051147; Edition: 2 References: 9; illus. incl. 1 table |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 6357 |
Serial |
190 |
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| Author |
Ziemkiewicz, P.; Skousen, J.; Simmons, J. |
| Title |
Cost benefit analysis of passive treatment systems |
Type |
Journal Article |
| Year |
2001 |
Publication |
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Issue |
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Pages |
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acid mine drainage; acidification; Augusta coal field; Big Bear Lake; carbonate rocks; coal mines; cost; dams; drainage basins; economics; ferric iron; Indiana; iron; limestone; metals; mines; optimization; oxidation; Pike County Indiana; pollution; Preston County West Virginia; pyrite; sedimentary rocks; South Fork Patoka River; spoils; sulfate ion; sulfides; surface water; United States; water pollution; water quality; water resources; water treatment; West Virginia 22, Environmental geology |
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West Virginia Surface Mine Drainage Task Force Symposium |
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Proceedings, 22nd West Virginia surface mine drainage task force symposium |
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2002-047125; Twenty-second West Virginia surface mine drainage task force symposium, Morgantown, WV, United States, April 3-4, 2001 References: 7; illus. incl. 9 tables; GeoRef; English |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 5766 |
Serial |
191 |
| Permanent link to this record |
