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Author (up) Blowes, D.W.; Ptacek, C.J.; Benner, S.G.; McRae, C.W.T.; Puls, R.W.
Title Treatment of dissolved metals using permeable reactive barriers Type Journal Article
Year 1998 Publication Groundwater Quality: Remediation and Protection Abbreviated Journal
Volume Issue 250 Pages 483-490
Keywords adsorption; aquifers; attenuation; dissolved materials; metals; nutrients; oxidation; pollutants; pollution; precipitation; reduction; water treatment Groundwater quality Pollution and waste management non radioactive Groundwater acid mine drainage aquifer pollution conference proceedings containment barrier metal tailings Canada Ontario Nickel Rim Mine United States North Carolina Elizabeth City mine water treatment
Abstract Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1).
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Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0144-7815 ISBN Medium
Area Expedition Conference
Notes Treatment of dissolved metals using permeable reactive barriers; Isip:000079718200072; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 8601 Serial 178
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Author (up) Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W.
Title Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation Type Book Chapter
Year 1998 Publication Groundwater Quality: Remediation and Protection Abbreviated Journal
Volume Issue Pages 451-457
Keywords acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology
Abstract A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997.
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Publisher IAHS-AISH Publication, vol.250 Place of Publication Editor Herbert, M.; Kovar, K.
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Series Editor Series Title Abbreviated Series Title
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ISSN ISBN 1901502554 Medium
Area Expedition Conference
Notes Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. Approved no
Call Number CBU @ c.wolke @ 16621 Serial 65
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