Houston, K. S., Milionis, P. N., Eppley, R. L., Harrington, J. M., & Harrington, J. G. (2005). Field Demonstration of In-Situ Treatment and Prevention of Acid Mine Drainage in the Abandoned Tide Mine, Indiana County, Pennsylvania.
Abstract: A field demonstration of the Green World Science® patented process technology was performed to address acid mine drainage (AMD) at an abandoned bituminous coal mine, the Tide Mine in Center Township, Indiana County, PA. ARCADIS owns an exclusive patent license of the Green World Science® process, which can be used in situ to transform an aerobic, AMD-producing mine pool to a biologically mediated, sulfate-reducing state. The Green World Science® process treats the entire mine pool to address the source of AMD in place. The project was conducted through a grant agreement between the Blacklick Creek Watershed Association, the Pennsylvania Department of Environmental Protection's Bureau of Abandoned Mine Reclamation, and ARCADIS. In conjunction with the characterization of mine pool hydraulics through injection of a bromide tracer, the in situ treatments implemented at Tide Mine include the initial addition of alkalinity to create an environment suitable for biological activity, injection of organic carbon into the mine pool to facilitate microbially mediated metals reduction and precipitation, and injection of carbon dioxide gas into the atmosphere above the mine pool to control the dominant source of oxygen that perpetuates the AMD process. Collectively, these treatments raised the pH from a baseline of approximately 2.5 to over 6 during the demonstration period. The mine pool subsequently maintains a pH above 5 through microbially produced (i.e., bicarbonate) alkalinity. Ferric iron has been reduced to non-detect concentrations within the anaerobic mine pool, and aluminum concentrations have decreased by approximately 30%, with additional metals removal expected as the system becomes controlled by ferrous sulfide precipitation. The injection of carbon dioxide gas into the mine workings decreased oxygen concentrations above the mine pool from over 20% (ambient air conditions) to less than 5% over approximately three months, thus mitigating the source of AMD within the mine.
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Calabrese, J. P., Sexstone, A. J., Bhumbla, D. K., Skousen, J. G., Bissonnette, G. K., & Sencindiver, J. C. (1994). Long-term study of constructed model wetlands for treatment of acid mine drainage. In Special Publication – United States. Bureau of Mines, Report: BUMINES-SP-06B-94 (406). Proceedings of the International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage; Volume 2 of 4; Mine drainage.
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Mustikkamaki, U. - P. (2000). Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation. Vuoriteollisuus = Bergshanteringen, 58(1), 44–47.
Abstract: Acid mine drainage (AMD) is one of the most serious environmental problems in the metal-mining industry. AMD is formed by the chemical and bacterial oxidation of sulphide minerals, and it is characterized by low pH values and high sulphate and metals content. The most common method to treat AMD is chemical neutralization. The chemical treatment requires high capital and operating costs and its use is problematic at the closed mines sites. Outokumpu has studied and used sulphate reducing bacteria (SRB) as an alternative method for the treatment of AMD. SRB existing in many natural anaerobic aqueous environments can reduce sulphate to sulphide which precipitates metals as extremely insoluble metal sulphides. Full scale experiments were begun in summer 1995 in the Ruostesuo open pit (depth 46 m) by adding liquid manure as a source of bacteria and press-juice as a growth substrate. The average Zn content of the whole column has decreased from 3,5 mg/l to 0,8 mg/l and below 25 m zinc is 0 mg/l. Similar results have been reached with nickel in the Kotalahti old nickel mine, where bacteria were brought in 1996. We have found that the same bacterial mechanism acts in peat-limestone filters, which Outokumpu has built at several mine sites since 1993.
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Sottnik, P., & Sucha, V. (2001). Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica. Mineralia Slovaca, 33(1), 53–60.
Abstract: A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers.
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Johnson, D. B., & Hallberg, K. B. (2002). Pitfalls of passive mine water treatment. Reviews in Environmental Science & Biotechnology, 1(5), 335–343.
Abstract: Passive (wetland) treatment of waters draining abandoned and derelict mine sites has a number of detrac-tions. Detailed knowledge of many of the fundamental processes that dictate the performance and longevity of constructed systems is currently very limited and therefore more research effort is needed before passive treatment becomes an “off-the-shelf” technology.
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