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Demchak, J., Morrow, T., Skousen, J., Donovan, J. J., & Rose, A. W. (2001). Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites. Geochemistry – Exploration, Environment, Analysis, 1(1), 71–80.
Abstract: Acid mine drainage (AMD) is a serious problem in many watersheds where coal is mined. Passive treatments, such as wetlands and anoxic limestone drains (ALDs), have been developed, but these technologies show varying treatment efficiencies. A new passive treatment technique is a vertical flow wetland or successive alkalinity producing system (SAPS). Four SAPS in Pennsylvania were studied to determine changes in water chemistry from inflow to outflow. The Howe Bridge SAPS removed about 130 mg l (super -1) (40%) of the inflow acidity concentration and about 100 mg l (super -1) (60%) iron (Fe). The Filson 1 SAPS removed 68 mg l (super -1) (26%) acidity, 20 mg l (super -1) (83%) Fe and 6 mg l (super -1) (35%) aluminium (Al). The Sommerville SAPS removed 112 mg l (super -1) (31%) acidity, exported Fe, and removed 13 mg l (super -1) (30%) Al. The McKinley SAPS removed 54 mg l (super -1) (91%) acidity and 5 mg l (super -1) (90%) Fe. Acid removal rates at our four sites were 17 (HB), 52 (Filson1), 18 (Sommerville) and 11 (McKinley) g of acid per m (super 2) of surface wetland area per day (g/m (super 2) d (super -1) ). Calcium (Ca) concentrations in the SAPS effluents were increased between 8 and 57 mg l (super -1) at these sites. Equilibrators, which were inserted into compost layers to evaluate redox conditions at our sites, showed that reducing conditions were generally found at 60 cm compost depths and oxidized conditions were found at 30 cm compost depths. Deeply oxidized zones substantiated observations that channel flow was occurring through some parts of the compost. The Howe Bridge site has not declined in treatment efficiency over a six year treatment life. The SAPS construction costs were equal to about seven years of NaOH chemical treatment costs and 30 years of lime treatment costs. So, if the SAPS treatment longevity is seven years or greater and comparable effluent water quality was achieved, the SAPS construction was cost effective compared to NaOH chemical treatment. Construction recommendations for SAPS include a minimum of 50 cm of compost thickness, periodic replacement or addition of fresh compost material, and increasing the number of drainage pipes underlying the limestone.
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Coulton, R., Bullen, C., & Hallett, C. (2003). The design and optimisation of active mine water treatment plants. Land Contam. Reclam., 11(2), 273–280.
Abstract: This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters.
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Laine, D. M., & Jarvis, A. P. (2003). Engineering design aspects of passive in situ remediation of mining effluents. Land Contam. Reclam., 11(2), 113–126.
Abstract: Passive treatment of contaminated effluents can offer a 'low cost' management opportunity to remediate drainages to the standards required by enforcement agencies. However, the initial cost of construction of passive treatment systems is significant and often in excess of that for active treatment systems. It is therefore important that the engineering design of the passive systems produces an effective and efficient scheme to enable the construction and maintenance costs to be minimised as far as possible. Possible parameters for the design of passive systems are suggested to seek to obtain uniformity in size and layout of treatment elements where this may be possible. Passive treatment systems include aeration systems, sedimentation ponds, aerobic and anaerobic wetlands, anoxic limestone drains and reducing alkalinity producing systems. Most active treatment systems also include passive elements in the treatment stream. The basic design considerations that should be considered to ensure the construction of efficient systems are discussed.
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Barton, C. D., & Karathanasis, A. D. (1998). Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage. Environ Geosci, 5(2), 43–56.
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Agency, U. S. E. P., & Development, O. of R. and. (2006). Active and semi-passive lime treatment of acid mine drainage at Leviathan Mine, California. Cincinnati, OH: National Risk Management Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency.
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