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Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Year |
1997 |
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AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Younger, P.L.; Neal, C.; House, W.A.; Leeks, G.J.L.; Marker, A.H. |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years |
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Journal Article |
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1997 |
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The Science of the Total Environment |
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194-195 |
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457-466 |
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acid mine drainage; acidic composition; acidification; Cornwall England; decision-making; degradation; discharge; England; Europe; Great Britain; hydrolysis; mines; planning; pollutants; pollution; remediation; retention; Scotland; soils; surface water; United Kingdom; Wales; waste disposal; water quality; Western Europe 22, Environmental geology |
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0048-9697 |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years; 1997-078352; Special issue References: 30; illus. Netherlands (NLD); GeoRef; English |
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CBU @ c.wolke @ 6259 |
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193 |
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Stewart, D.; Norman, T.; Cordery-Cotter, S.; Kleiner, R.; Sweeney, E.; Nelson, J.D. |
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Utilization of a ceramic membrane for acid mine drainage treatment |
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Journal Article |
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1997 |
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Tailings and Mine Waste '97 |
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453-460 |
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acid mine drainage; Black Hawk Colorado; Central City Colorado; ceramic materials; Colorado; cost; disposal barriers; geochemistry; Gilpin County Colorado; heavy metals; mines; organic compounds; pollution; remediation; surface water; tailings; United States; utilization; volatile organic compounds; volatiles; waste disposal mine water treatment |
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BASX Systems LLC has developed a treatment system based on ceramic membranes for the removal of heavy metals from an acid mine drainage stream. This stream also contained volatile organic compounds that were required to be removed prior to discharge to a Colorado mountain stream. The removal of heavy metals was greater than 99% in most cases. A decrease of 30% in chemicals required for treatment and a reduction by more than 75% in labor over a competing technology were achieved. These decreases were obtained for operating temperatures of less than 5 degrees C. This system of ceramic microfiltration is capable of treating many different types of acid mine waste streams for heavy metals removal. |
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90-5410-857-6 |
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Jan 13-17; Utilization of a ceramic membrane for acid mine drainage treatment; Isip:A1997bg96u00050; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8744 |
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135 |
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Becker, B.; Graff, M.; Näveke, R. |
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Biological Treatment of Overburden from Lignite Opencast Mining in Order to Avoid Seepage of Acid Mine Water |
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1997 |
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Proceedings, 6th International Mine Water Association Congress, Bled, Slovenia |
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2 |
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283-291 |
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coal mining mine water acid mine water Germany treatment laboratory studies |
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Biological Treatment of Overburden from Lignite Opencast Mining in Order to Avoid Seepage of Acid Mine Water; 1; FG 6 Abb.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9527 |
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460 |
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Author |
Bertrand, S. |
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Title |
Performance of a nanofiltration plant on hard and highly sulphated water during two years of operation |
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Journal Article |
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Year |
1997 |
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Desalination |
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113 |
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2-3 |
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277-281 |
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mine water treatment |
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A highly sulphated, hard water from a flooded iron mine was treated by nanofiltration for the production of drinking water (125 m(3)/h). This paper introduces the context and summarizes the configuration and operating conditions of the plant. The process performance in terms of product water quality and permeability during the first 2 years is presented and discussed. |
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Performance of a nanofiltration plant on hard and highly sulphated water during two years of operation; Wos:000071218200023; Times Cited: 5; ISI Web of Science |
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CBU @ c.wolke @ 17153 |
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134 |
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