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Carlson, L.; Kumpulainen, S. |
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Retention of harmful elements by ochreous precipitates of iron |
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Journal Article |
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2001 |
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Tutkimusraportti Geologian Tutkimuskeskus |
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- |
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154 |
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30-33 |
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Surface water quality Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 9) geological abstracts: environmental geology (72 14 2) iron oxide precipitation chemistry sulfate arsenate heavy metal pH water pollution remediation |
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Abstract |
The capability of soil fines to fix harmful elements, e.g. heavy metals and arsenic, depends on specific surface area and other characteristics, such as surface charge. In the pH-range typical of natural waters (pH 5,5-7,5), the surfaces of fine-grained silicate particles and manganese oxides are negatively charged; consequently cations, such as heavy metals, fix effectively to them. The iron oxide surfaces are usually positively charged and typically fix anions, such as sulphate and arsenate. Retention of anions is especially extensive to precipitates formed from acid mine drainage (pH 2,5-5,0). For example, precipitates found at Paroistenjarvi mine, Finland, contain more than 70 g/kg of arsenic (dry matter). Adsorbed anions, e.g. sulphate, enhance the capacity of precipitate to fix heavy metal cations in low-pH environments. |
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L. Carlson, Tehtaankatu 25 A 4, Helsinki FIN-00150, Finland liisa.carlson@kolumbus.fi |
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0781-4240 |
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Retention of harmful elements by ochreous precipitates of iron; 2392974; Oksidiset rautasaostumat haitallisten aineiden pidattajina. Finland 7; Geobase |
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CBU @ c.wolke @ 17533 |
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421 |
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Ciftci, H.; Akcil, A. |
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Asidik maden drenajinin (AMD) giderilmesinde uygulanan biyolojik yontemler. Biological methods applied in the treatment of acid mine drainage (AMD) |
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Journal Article |
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2006 |
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Madencilik = The = Journal of the Chamber of Mining Engineers of Turkey |
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45 |
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1 |
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35-45 |
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acid mine drainage biodegradation methods microorganisms oxidation pollutants pollution remediation sulfides 22, Environmental geology |
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Acidic mine drainage (AMD) is a serious environmental problem in mining areas throughout the world. AMD occurs as a result of the natural oxidation of sulfide minerals when they are exposed to oxygen and water during their disposal and storage at the mining areas. Because it includes low pH and high concentrations of dissolved metals and sulphates, AMD can potentially damage to the environment. If the formation of AMD can't be prevented and controlled, it must be collected and treated to remove acidity and reduce the concentration of heavy metals and suspended solids before its release to the environment. Different types of microorganisms in the treatment of AMD can play a very important role in the development and the application of microbiological prevention, control and treatment technologies. The purpose of this article is to give information about the passive biological methods used in the treatment and the control of AMD and the role of microorganisms in these methods. |
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0024-9416 |
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Asidik maden drenajinin (AMD) giderilmesinde uygulanan biyolojik yontemler. Biological methods applied in the treatment of acid mine drainage (AMD); 2006-075215; References: 58 Turkey (TUR); GeoRef; Turkish |
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CBU @ c.wolke @ 16444 |
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416 |
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Conca, J.L.; Wright, J. |
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An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Author |
Davis, L.K. |
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Constructed wetlands handbook |
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Book Chapter |
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1994 |
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Special Publication – United States. Bureau of Mines, Report: BUMINES-SP-06B-94 |
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409 |
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acid mine drainage; constructed wetlands; mining geology; pollution; remediation; waste disposal; wetlands 22, Environmental geology |
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Proceedings of the International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage; Volume 2 of 4; Mine drainage |
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Constructed wetlands handbook; GeoRef; English; 2007-045261; International land reclamation and mine drainage conference; International conference on The abatement of acidic drainage, Pittsburgh, PA, United States, April 24-29, 1994 |
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CBU @ c.wolke @ 6633 |
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406 |
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Author |
Dillard, G. |
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A win-win way to clean up by changing ionic state, new process can precipitate heavy metals |
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2000 |
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Pay Dirt |
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734 |
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10-11 |
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acid mine drainage; California; chemical composition; companies; environmental analysis; environmental management; heavy metals; ion exchange; ions; metal ores; metals; mining; pollutants; pollution; precipitation; processes; remediation; soils; surface water; United States; water treatment 22, Environmental geology |
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A win-win way to clean up by changing ionic state, new process can precipitate heavy metals; 2004-029026; illus. United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5822 |
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401 |
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