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Author |
Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W. |
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Title |
Evaluation of in situ layers for treatment of acid mine drainage: A field comparison |
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Journal Article |
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Year |
2006 |
Publication |
Water Res |
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40 |
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9 |
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1816-1826 |
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mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment |
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Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell. |
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0043-1354 |
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May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct |
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CBU @ c.wolke @ 10040 |
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49 |
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Tsukamoto, T.K.; Miller, G.C. |
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Title |
Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage |
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Journal Article |
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Year |
1999 |
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Water Res. |
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33 |
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6 |
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1365-1370 |
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mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov |
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Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd. |
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0043-1354 |
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Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 10197 |
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50 |
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Author |
Deul, M. |
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Title |
Limestone for controlling acid mine drainage and for the treatment of acid mine water |
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Journal Article |
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1976 |
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Int. J. Rock Mech. Min. Sci. and Geomech. Abstr. |
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13 |
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8 |
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A92-111 |
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1365-1609 |
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Aug; Limestone for controlling acid mine drainage and for the treatment of acid mine water; Proc. 10th Forum Geol. Ind. Miner. Ohio Dept. Nat. Res. Div. Geol. Surv. Report 1, 1974, P43-46; Science Direct |
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CBU @ c.wolke @ 15103 |
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51 |
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Ericsson, B.; Hallmans, B. |
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Title |
Treatment and Disposal of Saline Waste-water from Coal-mines in Poland |
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1994 |
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Desalination |
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98 |
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1-3 |
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239-248 |
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mine water |
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Some Polish coal mines are reviewed with respect to the disposal of saline wastewater into rivers and its environmental impact. The drainage water from mines has a daily contribution of, in the order of magnitude, 6,500 tons chlorides (Cl-) and 0.5 tons sulphates (SO42-) to the rivers Wisla and Odra. The river Wisla contributes to about 55 % of the water resources in Poland. This report is based on a part of a commission for the Ministry of Environmental Protection, National Resources and Forestry ofPoland by COWI-VBB VIAK joint venture.Different treatment and disposal schemes are described and compared from a technical-economical point of view, out of which methods for desalination with zero discharge as well as deep well injection are the most promising ones.The desalination methods include reverse osmosis (RO) plant, thermal powered desalination and crystallization plant as well as facilities for dewatering and drying of sodium chloride (NaCl) to be sold in Poland and/or on the export market, The valuable main products are potable water, boiler feed water and sodium chloride. A special problem in this connection may be the radioactivity in the wastewater from some of the mines. Special treatment methods for radioactivity removal in the selected treatment and disposal scheme for the mine wastewater are discussed with respect to the effects of radioactivity on the saleability of the recovered salt. In addition methods for recovery of the by-products magnesium hydroxide, iodine and bromine are considered from the point of view of economy and environmental protection.Finally, the desalination project in Katowice for the coal mines Debiensko and Budryk is now in the end of the construction phase. Some modifications of the original design ace shown. |
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0011-9164 |
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Treatment and Disposal of Saline Waste-water from Coal-mines in Poland; Isi:A1994pp05300022; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17337 |
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52 |
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Ericsson, B.; Hallmans, B. |
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Title |
Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland |
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Journal Article |
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1996 |
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Desalination |
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105 |
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1-2 |
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115-123 |
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mine water |
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The drainage water from mines in Poland has a daily contribution of, in the order of magnitude, 6,500 tons of chlorides and 0.5 ton of sulphates to the rivers Vistula (Wisla) and Oder (Odra). The largest amounts of these salts, about 78%, derive from 18 mines located mainly in the Katowice mine district. The high salt content in the water from the Vistula prevents at present its use in agriculture and causes tremendous economic losses due to corrosion attacks on pipes, machines, etc., within the industry. At present only about 4% of the river water can be classified as drinking water. To combat this problem a desalination project in Katowice has now almost been completed, including advanced treatment of wastewater for zero discharge from the two adjacent coal mines, Debiensko and Budryk. It implies elimination of 310 tons/d of salt discharge to the Odra River. The complete treatment processes are divided into three main sections: (1) pretreatment before reverse osmosis (RO) of about 12,400 m3/d drainage water from the two mines with a salinity of around 16,000 mg/l TDS on the average; (2) RO plant including post-treatment of the RO permeate; (3) a thermal plant for concentration of brine (about 4,600 m3/d) and separation of sodium chloride (NaCl) by crystallization, centrifuging and drying. The RO pretreatment includes algicide dosing in a storage tank, disinfection, flocculation/sedimentation and dual media filtration as well as granular activated carbon filtration. After a two-stage microfilter system (50 μ and 5 μ, respectively), the pretreated water is desalinated at 6-7 MPa in a RO system with spiral wound RO membranes. The RO permeate is decarbonated in a part-flow followed by addition of chemicals for disinfection and increase of the temporary hardness before distribution in the drinking water net. The flow into the thermal plant consists of the RO reject (about 2,700 m3/d) with a salinity of around 80 g/l TDS and the brine flow (about 1,870 m3/d) from the Budryk mine with about the same salinity. The first section of the thermal plant is composed of two brine concentrators, designed by Resources Conservation Company (RCC), USA. By using the seed crystal recycling technique it is possible to concentrate the feed to near the precipitation point for NaCl. The second section of the thermal plant includes one crystallizer for production of NaCl, two pusher centrifuges for salt removal from supersaturated brine and one fluidized bed dryer. The crystallizer is a forced circulation submerged-tube evaporator equipped with a mechanical vapor compressor. An additional section is also planned to be constructed for treatment of the purge from the crystallizer in order to recover other valuable chemical products and distillate. The process is fully automatic and controlled by programmable logic controllers. The plant has finally been designed by Energotechnika, Poland, after preparation of technical and economical planning of the project in coordination with Nordcap Ltd., RCC and VBB Viak-SWECO, Stockholm. In the summer 1994 the thermal plant was started up, and the RO plant is expected to be in operation during the spring 1995. The paper covers the project design with illustrations of the main parts of the plant and summarizes the results of the initial operation. |
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0011-9164 |
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June; Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9451.pdf; Science Direct |
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CBU @ c.wolke @ 17274 |
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53 |
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