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Bearcock, J.M. |
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Title |
Accelerated precipitation of ochre for mine water remediation |
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2006 |
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Geochim. Cosmochim. Acta |
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70 |
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18 |
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A42-A42 |
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mine water treatment |
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Accelerated precipitation of ochre for mine water remediation; Wos:000241374200094; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16919 |
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104 |
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Macklin, M.G. |
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A geomorphological approach to the management of rivers contaminated by metal mining |
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Journal Article |
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2006 |
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Geomorphology |
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79 |
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3-4 |
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423-447 |
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mine water treatment |
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As the result of current and historical metal mining, river channels and floodplains in many parts of the world have become contaminated by metal-rich waste in concentrations that may pose a hazard to human livelihoods and sustainable development. Environmental and human health impacts commonly arise because of the prolonged residence time of heavy metals in river sediments and alluvial soils and their bioaccumulatory nature in plants and animals. This paper considers how an understanding of the processes of sediment-associated metal dispersion in rivers, and the space and timescales over which they operate, can be used in a practical way to help river basin managers more effectively control and remediate catchments affected by current and historical metal mining. A geomorphological approach to the management of rivers contaminated by metals is outlined and four emerging research themes are highlighted and critically reviewed. These are: (1) response and recovery of river systems following the failures of major tailings dams; (2) effects of flooding on river contamination and the sustainable use of floodplains; (3) new developments in isotopic fingerprinting, remote sensing and numerical modelling for identifying the sources of contaminant metals and for mapping the spatial distribution of contaminants in river channels and floodplains; and (4) current approaches to the remediation of river basins affected by mining, appraised in light of the European Union's Water Framework Directive (2000/60/EC). Future opportunities for geomorphologically-based assessments of mining-affected catchments are also identified. (c) 2006 Elsevier B.V. All rights reserved. |
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A geomorphological approach to the management of rivers contaminated by metal mining; Wos:000241084500014; Times Cited: 1; ISI Web of Science |
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CBU @ c.wolke @ 16934 |
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105 |
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Sierra-Alvarez, R. |
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Biological treatment of heavy metals in acid mine drainage using sulfate reducing bioreactors |
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Journal Article |
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2006 |
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Water Sci. Technol. |
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54 |
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2 |
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179-185 |
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mine water treatment |
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The uncontrolled release of acid mine drainage (AMD) from abandoned mines and tailing piles threatens water resources in many sites worldwide. AMD introduces elevated concentrations of sulfate ions and dissolved heavy metals as well as high acidity levels to groundwater and receiving surface water. Anaerobic biological processes relying on the activity of sulfate reducing bacteria are being considered for the treatment of AMD and other heavy metal containing effluents. Biogenic sulfides form insoluble complexes with heavy metals resulting in their precipitation. The objective of this study was to investigate the remediation of AMD in sulfate reducing bioreactors inoculated with anaerobic granular sludge and fed V with an influent containing ethanol. Biological treatment of an acidic (pH 4.0) synthetic AMD containing high concentrations of heavy metals (100 Mg Cu2+vertical bar(-1); 10 mg Ni2+vertical bar(-1), 10 mg Zn2+vertical bar(-1)) increased the effluent pH level to 7.0-7.2 and resulted in metal removal efficiencies exceeding 99.2%. The highest metal precipitation Cn rates attained for Cu, Ni and Zn averaged 92.5, 14.6 and 15.8 mg metal l(-1) of reactor d(-1). The results of this work demonstrate that an ethanol-fed sulfidogenic reactor was highly effective to remove heavy metal contamination and neutralized the acidity of the synthetic wastewater. |
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Biological treatment of heavy metals in acid mine drainage using sulfate reducing bioreactors; Wos:000240449300024; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16943 |
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106 |
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Bamforth, S.M. |
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Title |
Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates |
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Journal Article |
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2006 |
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Appl. Geochem. |
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21 |
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8 |
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1274-1287 |
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mine water treatment |
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Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in continuous-flow reactors. For all substrates except quartzite, Mn was removed from the mine water during this period, and Mn minerals precipitated in all cases. In addition, the plastic from which the reactor was made played a role in Mn removal. Manganese oxyhydroxides were formed in all the reactors; however, Mn carbonates (specifically kutnahorite) were only identified in the reactors containing quartzite and on the reactor plastic. Magnesium-rich calcites were identified in the dolomite and magnesite reactors, suggesting that the Mg from the substrate minerals may have inhibited Mn carbonate formation. Biofilm community development and composition on all the substrates was also monitored over the 3-month period using denaturing gradient gel electrophoresis (DGGE). The DGGE profiles in all reactors showed no change with time and no difference between substrate types, suggesting that any microbiological effects are independent of mineral substrate. The identification of Mn carbonates in these systems has important implications for the design of Mn treatment systems in that the provision of a carbonate-rich substrate may not be necessary for successful Mn precipitation. (c) 2006 Elsevier Ltd. All rights reserved. |
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Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates; Wos:000240297600004; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16916 |
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107 |
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Author |
Jong, T. |
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Title |
Microbial sulfate reduction under sequentially acidic conditions in an upflow anaerobic packed bed bioreactor |
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Journal Article |
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Year |
2006 |
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Water Research |
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40 |
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13 |
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2561-2571 |
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mine water treatment |
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The aim of this study was to operate an upflow anaerobic packed bed reactor (UAPB) containing sulfate reducing bacteria (SRB) under acidic conditions similar to those found in acid mine drainage (AMD). The UAPB was filled with sand and operated under continuous flow at progressively lower pH and was shown to be capable of supporting sulfate reduction at pH values of 6.0, 5.0, 4.5, 4.0 and 3.5 in a synthetic medium containing 53.5 mmol l(-1) lactate. Sulfate reduction rates of 553-1052 mmol m(-3) d(-1) were obtained when the influent solution pH was progressively lowered from pH 6.0 to 4.0, under an optimal flow rate of 2.61 ml min(-1). When the influent pH was further lowered to pH 3.5, sulfate reduction was substantially reduced with only about 1% sulfate removed at a rate of 3.35 mmol m(-3) d(-1) after 20 days of operation. However, viable SRB were recovered from the column, indicating that the SRB population was capable of surviving and metabolizing at low levels even at pH 3.5 conditions for at least 20 days. The changes in conductivity in the SRB column did not always occur with changes in pH and redox potential, suggesting that conductivity measurements may be more sensitive to SRB activity and could be used as an additional tool for monitoring SRB activity. The bioreactor containing SRB was able to reduce sulfate and generate alkalinity even when challenged with influent as low as pH 3.5, indicating that such treatment systems have potential for bioremediating highly acidic, sulfate contaminated waste waters. (c) 2006 Elsevier Ltd. All rights reserved. |
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Microbial sulfate reduction under sequentially acidic conditions in an upflow anaerobic packed bed bioreactor; Wos:000239469400012; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16929 |
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108 |
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