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Benner, S. G., Blowes, D. W., & Ptacek, C. J. (1997). A full-scale porous reactive wall for prevention of acid mine drainage. Ground Water Monitoring and Remediation, 17(4), 99–107.
Abstract: The generation and release of acidic drainage containing high concentrations of dissolved metals from decommissioned mine wastes is an environmental problem of international scale. A potential solution to many acid drainage problem is the installation of permeable reactive walls into aquifers affected by drainage water derived from mine waste materials. A permeable reactive wall installed into an aquifer impacted by low-quality mine drainage waters was installed in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The reactive mixture, containing organic matter, was designed to promote bacterially mediated sulfate reduction and subsequent metal sulfide precipitation. The reactive wall is installed to an average depth of 12 feet (3.6 m) and is 49 feet (15 m) long perpendicular to ground water flow. The wall thickness (flow path length) is 13 feet (4 m). Initial results, collected nine months after installation, indicate that sulfate reduction and metal sulfide precipitation is occurring. Comparing water entering the wall to treated water existing the wall, sulfate concentrations decrease from 2400 to 4600 mg/L to 200 to 3600 mg/L; Fe concentration decrease from 250 to 1300 mg/L to 1.0 to 40 mg/L, pH increases from 5.8 to 7.0; and alkalinity (as CaCO<inf>3</inf>) increases from 0 to 50 mg/L to 600 to 2000 mg/L. The reactive wall has effectively removed the capacity of the ground water to generate acidity on discharge to the surface. Calculations based on comparison to previously run laboratory column experiments indicate that the reactive wall has potential to remain effective for at least 15 years.
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Cravotta, C. A., III, Watzlaf, G. R., Naftz, D. L., Morrison, S. J., Fuller, C. C., & Davis, J. A. (2002). Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients.. Amsterdam: Academic Press.
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Eger, P., Melchert, G., Antonson, D., & Wagner, J. (1993). Magnesium hydroxide as a treatment for acid mine drainage in northern Minnesota. In B. A. Zamora, & R. E. Connolly (Eds.), Proceedings of the Annual National Meeting – American Society for Surface Mining and Reclamation, vol.10 (pp. 204–217). The challenge of integrating diverse perspectives in reclamation.
Abstract: Three alkaline materials were investigated for their suitability to treat acid mine drainage generated by a research facility located at a remote site in northern Minnesota. The materials investigated were hydrated lime, sodium hydroxide, and magnesium hydroxide. All three reagents were successful at raising pH and removing trace metals from the drainage, but the magnesium hydroxide had the added benefit of producing a maximum pH of approximately 9.5, while the other two reagents resulted in pH values of 12 and greater. In addition, the magnesium hydroxide was available as a high solid content slurry (58%) which simplified application and handling, and which produced the lowest volume of sludge of the materials tested.
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Gale, J. E., MacLeod, R., & Bursey, G. (1999). The role of hydrogeology in developing effective mine water control programs in fractured porous rocks Resources development and Earth science; environmental and economic issues (Abstract). In R. K. Pickerill, S. M. Barr, & G. L. Williams (Eds.), Atlantic Geology (172). 35.
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