Abstract: Much work has been undertaken on the design of treatment systems to remove iron from ochreous mine water discharges. Unlike iron, manganese removal is far more difficult and generally requires active chemical dosing rather than passive treatment. The need for manganese removal can therefore significantly change the economics, management attention and sustainability of a site. Understanding natural attenuation of manganese in river systems is therefore key to deciding whether (active) manganese treatment is needed to protect downstream receptors. Nuttall (2002, this volume) describes the effectiveness of the passive treatment system at Whittle in reducing both iron and manganese concentrations in ochreous mine waters. This paper discusses the results of in-river monitoring and provides evidence for manganese removal downstream of the discharge point. In addition to dilution, attenuation appears to be in the order of 20 to 50%, depending on relative rates of mine water discharge and river flows. Such attenuation means that active treatment may not be needed for the long-term operation of the Whittle scheme. Operation of the scheme commenced in July 2002, with monitoring to further examine evidence for manganese attenuation and any impact on the ecology of the recipient watercourses.

Abstract: Seven kilometres of the River Pelenna in South Wales were impacted for approximately 30 years by discharges from abandoned coal mines. Elevated iron and low pH caused significant ochreous staining and had detrimental effects on the river ecology. The River Pelenna Mine water project constructed a series of passive wetland treatment systems to treat these discharges. Monitoring of the performance and environmental benefits of these has been undertaken as part of an Environment Agency R&D project. This project has assessed the changes in water quality as well as monitoring populations of invertebrates, fish and birds between 1993 and 2001. Performance data from the wetlands show that on average the three systems are removing between 82 and 95% of the iron loading from the mine waters. In the rivers downstream, the dissolved iron concentration has dropped to below the Environmental Quality Standard (EQS) of 1 mg/L for the majority of the time. Increases in pH downstream of the discharges have also been demonstrated. Trout (Salmo trutta) recovered quickly following mine water treatment, returning the next year to areas that previously had no fish. Intermittent problems with overflows from the treatment systems temporarily depleted the numbers, but the latest data indicate a thriving population. The overflow problems and also background episodes of acidity have affected the recovery of the riverine invertebrates. However, there have been gradual improvements in the catchment, and in the summer of 2001 most sites held faunas which approached those found in unpolluted controls. Recovery of the invertebrate fauna is reflected in marked increases in the breeding success of riverine birds between 1996 and 2001. This study has shown that constructed wetlands can be an effective, low cost and sustainable solution to ecological damage caused by abandoned mine drainage.

Abstract: Environmentally compatible Waste Management schemes employed by the European extractive industry for the development of new projects, and applied in operating sulphide mines, are presented in this study. Standard methodologies used to assess the geotechnical and geochemical properties of the solid wastes stemming from mining and processing of sulphidic metal ores are firstly given. Based on waste properties, the measures applied to ensure the environmentally safe recycling and disposal of sulphidic wastes are summarised. Emphasis is given on the novel techniques developed to effectively prevent and mitigate the acid drainage phenomenon from sulphidic mine wastes and tailings. Remediation measures taken to minimise the impact from waste disposal sites in the post-closure period are described.