Abstract: The technical knowledge and practical experience accumulated by industry and others in abating acid mine drainage (AMD) is being proactively applied at every phase of the mine life cycle. This paper traces the mine life cycle from exploration to post closure monitoring and maintenance, and reviews AMD abatement measures that have become an integral component of exploration and mining activities. Attention is increasingly being given to evaluating AMD potential as part of exploration work, and studies related to project feasibility and design. Mining, mineral processing and waste management options are selected taking into consideration their suitability to inhibit AMD. These inhibition measures are typically committed to in closure plans submitted at the permitting stage. Mines are operated and decommissioned, often progressively, as planned and in accordance with environmental protection policies. Es wird über das Problem der Säurebildung aus sulfidischen Aufbereitungsbergen und taubem Gestein im Verlauf des Existenzzyklus eines Bergwerkes berichtet. In Kanada werden seit etwa 10 Jahren intensive Forschungen für Vorhersage, Kontrolle und Eindämmung von Saürebildungen im Bergbau betrieben. Schwerpunkt ist dabei die sulfidische Oxidation (2FeS2 + 7O2 = 2FeSO4 + 2H2SO4) unter Einwirkung verschiedener physikalischer, geochemischer und biologischer Faktoren. Diese Reaktion führt zu einem Komplex weiterer chemischer Reaktionen unter Bildung von zusätzlicher Säure und Lösung von Metallen. Daraus ergeben sich zwei Hauptmöglichkeiten diesen Prozeß zu steuern: 1. die Sulfidoxidation verhindern, 2. den Oxidationsprozeß verlangsamen. Mit dem heutigen Wissensstand ist es möglich, das Säurebildungspotential von Aufbereitungsbergen zu bestimmen, den Prozeß der Sulfidoxidation von Mineralen unter bestimmten physikalischen, geochemischen und biologischen Bedingungen zu modellieren und die Säurebildung von Aufbereitungsbergen und sulfidischen Gesteinen einzudämmen. Im einzelnen werden Maßnahmen zur Bewertung des Säurebildungspotentials und zur Kontrolle und Reduzierung dieses Prozesses während der Existenzstadien Exploration, Durchführbarkeitsstudie und Genehmigung, Gewinnung und Stillegung eines Bergwerkes erläutert. An Beispielen wird gezeigt, daß bei rechtzeitgem Erkennen des Säurebildungspotentials in der Phase der Exploration Verfahren und Maßnahmen bezüglich Aufbereitung, Umgang mit Aufbereitungsbergen ausgewählt werden können.

Abstract: Diversion wells implement a fluidized bed of limestone for the treatment of acid water resulting from acid mine drainage or acid precipitation. This study was undertaken to better understand the operation of diversion wells and to define the physical and chemical factors having the greatest impact on the neutralization performance of the system. The study site was located near Lick Creek, a tributary stream of Babb Creek, near the Village of Arnot in Tioga County, Pennsylvania. Investigative methods included collection and analysis of site water quality and limestone data and field study of this as well as other diversion well sites. Analysis of data led to these general conclusions: The site received surface water influenced by three primary sources 1) precipitation, 2) mine drainage baseflow, and 3) melted snow. Water mostly influenced by precipitation events and mine drainage baseflow was more acidic than water influenced by melting snow conditions. The diversion wells were generally able to treat only half or less of the total stream flow of Lick Creek and under extremely high flow conditions the treatment provided was minimal. A range of flow conditions were identified which produced the best performance for the two diversion wells. Treatment produced by the system decreased through the loading cycle and increases to a maximum value after each weekly refilling of limestone. Fine grained sediment in the stream was found to be limestone of the same general composition as the material placed within the wells. Neutralization of acid water was largely due to microscopic particles rather than the limestone sediment discharged to the stream. Additional downstream buffering due to the limestone sediment physically discharged from the vessels was not apparent. Diversion well systems are inexpensive and simple to construct. In addition, the systems were found to be highly reliable and able to effectively treat acid water resulting from mine drainage and acid precipitation. Diversion wells provide better treatment when the treatment site is located at the source of the acidity (such as a mine discharge), rather than at the receiving stream. Systems should be designed with 15 to 20 feet of hydraulic head and the site must have year-round access. Diversion well systems require weekly addition of limestone gravel to the vessels to facilitate continual treatment. A great deal of commitment is necessary to maintain a diversion well system for long periods of time. These systems are more economical and require less attention that conventional chemical treatment of acid water. However, these systems require more attention that traditional passive treatment methods for treatment of acid, including mine drainage.

Abstract: An investigation of the effects of ozone and ozone-induced hydroxyl radical on reducing whole affluent toxicity is described and discussed relative to the application of ozone for industrial water treatment. Results from operation of an ozone system treating industrial affluent from a lead and zinc mine in Colorado are presented. The mine discharges 1,000 gpm of wastewater into a tributary of the Arkansas River and has historically exceeded Whole Effluent Toxicity (WET) limits and on occasion has exceeded numeric limits for copper, ammonia, and cyanide. Based on results of a Toxicity Identification Evaluation (TIE) conducted on the effluent and individual process waste streams, the source of effluent toxicity is believed to be primarily associated with organic reagents used in the milling process.